| # | Title | Artist | Rating | Length |
|---|
| 1 | Viva Tonight Overture | Darcey Bussell & Katherine Jenkins | | 6:26 |
| 2 | Fred Astaire: Putting on the Ritz | Darcey Bussell | | 3:54 |
| 3 | Fred Astaire: Stepping Out | Darcey Bussell | | 4:35 |
| 4 | Doris Day: The Deadwood Stage | Katherine Jenkins | | 3:50 |
| 5 | Doris Day: Secret Love | Katherine Jenkins | | 3:59 |
| 6 | Audrey Hepburn: Basal Metabolism | Darcey Bussell | | 2:22 |
| 7 | Audrey Hepburn: How Long Has This Been Going On? | Darcey Bussell | | 1:26 |
| 8 | Barbra Streisand: People- recording engineer:
- Toby Alington (in 2008)
- sound engineer:
- Dick Rabel (in 2008)
- engineer:
- Stewart Kennett (in 2008)
- audio engineer:
- Harold Loveday (in 2008), Ollie Nesham (in 2008), Tim Summerhayes (in 2008) and Ben Woodgate (in 2008)
- producer:
- Colin Fay
- mixer:
- Toby Alington
- vocals:
- Katherine Jenkins (in 2008)
- orchestra:
- Viva La Diva Orchestra (in 2008)
- conductor:
- Steve Sidwell (in 2008)
- video director:
- Matt Askem (in 2008)
- recorded at:
- The O2 Arena in Greenwich, London , England, United Kingdom (in 2008)
- live cover recording of:
- People
- lyricist:
- Bob Merrill (in 1963)
- composer:
- Jule Styne (in 1963)
- publisher:
- Broadway Tunes LLC dba Songs of Funny Girl, Chappell & Co., Chappell & Co., Inc. , Chappell Music , Chappell Music Ltd. and Warner Chappell Music Ltd.
- sub-publisher:
- ヤマハミュージックエンタテインメントホールディングス and ワーナー・チャペル音楽出版 Synch事業部
- part of:
- Funny Girl
| Katherine Jenkins | | 3:56 |
| 9 | Scott Joplin: Elite Syncopations (solo) | Darcey Bussell | | 2:39 |
| 10 | Scott Joplin: Elite Syncopations (pas de deux) | Darcey Bussell & Gary Avis | | 3:06 |
| 11 | Édith Piaf: La Vie en rose | Katherine Jenkins | | 4:38 |
| 12 | Cyd Charisse: Girl Hunt Ballet | Darcey Bussell | | 4:31 |
| 13 | Natalie Wood: Let Me Entertain You | Katherine Jenkins | | 4:07 |
| 14 | Shirley Bassey: Big Spender | Viva La Diva Orchestra | | 2:26 |
| 15 | Marilyn Monroe: Diamonds Are a Girl’s Best Friend | Darcey Bussell & Katherine Jenkins | | 3:02 |
| 16 | Carmen: Chanson bohème | Katherine Jenkins | | 4:29 |
| 17 | Flamenco (interlude) / [The Worm Song] | Darcey Bussell / Katherine Jenkins | | 7:55 |
| 18 | Judy Garland: The Man That Got Away | Katherine Jenkins | | 5:38 |
| 19 | Moira Shearer: The Red Shoes | Darcey Bussell | | 11:13 |
| 20 | Maria Callas: Una voce poco fa | Katherine Jenkins | | 8:05 |
| 21 | Bob Fosse: Everything Old Is New Again | Darcey Bussell & Katherine Jenkins | | 1:54 |
| 22 | Bob Fosse: Without Rhythm | Alan Burkitt, Darcey Bussell & Katherine Jenkins | | 1:48 |
| 23 | Bob Fosse: You Can’t Do Wrong Doing Right | Katherine Jenkins | | 2:55 |
| 24 | Bob Fosse: My Sister Eileen | Viva La Diva Orchestra | | 2:49 |
| 25 | Bob Fosse: Finale | Darcey Bussell & Katherine Jenkins | | 4:56 |
| 26 | Viva Tonight Reprise | Darcey Bussell & Katherine Jenkins | | 3:55 |
| 27 | Interview with Darcey and Katherine | Darcey Bussell & Katherine Jenkins | | 15:49 |